新型键合纤维素手性固定相的制备及其拆分性能评价

键合型多糖手性固定相因具有化学稳定性高和溶剂耐受性好的特点而受到研究者的极大关注。采用施陶丁格（Staudinger）反应将6-叠氮-6-脱氧纤维素-3,5-二氯苯基氨基甲酸酯键合到氨丙基硅胶上得到一种新的键合型手性固定相（ImCel）,研究了其手性分离性能,并探讨了非常规流动相（如氯仿、四氢呋喃等）的影响。结果表明,在20对手性化合物中,17对在合适的流动相下得到基线分离。ImCel在正相条件下的分离性能优于反相条件,且在含氯仿的流动相中仍对手性化合物表现出良好的分离能力。在分离一系列芴甲氧羰基（fmoc）-氨基酸衍生物时,ImCel与键合6-叠氮-6-脱氧纤维素-3,5-二甲基苯基氨基甲酸酯的手性固定相表现出互补性,出现了固定相改变引起的对映体洗脱反转现象。本研究丰富了键合型多糖手性固定相的种类和合成方法,为开发新的键合型手性固定相提供了参考。     

Elastic and thermodynamic properties of vanadium nitride under pressure and the effect of metallic bonding on its hardness

By the particle-swarm optimization method, it is predicted that tetragonal P42mc, 141md, and orthorhombic Amm2 phases of vanadium nitride （VN） are energetically more stable than NaCl-type structure at 0 K. The enthalpies of the predicted three new VN phases, along with WC, NaC1, AsNi, CsCl type structures, are calculated each as a function of pressure. It is found that VN exhibits the WC-to-CsCl type phase transition at 256 GPa. For the considered seven crystal- lographic VN phases, the structures, elastic constants, bulk moduli, shear moduli, and Debye temperatures are investigated. Our calculated equilibrium structural parameters are in very good agreement with the available experimental results and the previous theoretical results for the NaC1 phase. The Debye temperatures of VN predicted three novel phases, which are all higher than those of the remaining structures. The elastic constants, thermodynamic properties, and elastic anisotropies of VN under pressure are obtained and the mechanical stabilities are analyzed in detail based on the mechanical stability criteria. Moreover, the effect of metallic bonding on the hardness of VN is also investigated, which shows that VNs in P42mc, 141md, and Amm2 phases are potential superhard phases. Further investigation on the experimental level is highly recommended to confirm our calculations presented in this paper.     

Dynamics of rotator chain with dissipative boundary

We study the deternfinistic dynanfics of rotator chain with purely mechanical driving on the boundary by stability analysis and numerical sinmlation. Globally synchronous rotation, clustered synchronous rotation, and split synchronous rotation states are identified. In particular, we find that the single-peaked wariance distribution of angular momenta is the consequence of the deterministic dynamics. As a result, the operational definition of temperature used in the previous studies on rotator chain should be revisited.     

精确延时控制爆破振动的实验研究

为了探讨电子雷管在降低爆破振动和改善岩石破碎效果方面的作用机理,基于地震波传播过程中的能量变化,给出了孔间毫秒延时时间的计算公式。根据目前国内露天矿生产实际,设计并开展了模型实验。实验结果表明,合理的孔间延时控制能够降低爆破振动。在本文的模型实验中,12 ms延时间隔下爆破振动瞬时能量最大值分别是2、7和9 ms延时间隔下爆破振动瞬时能量最大值的19%、25%和36%,4和12 ms延时间隔下爆破振动速度峰值最大值是其他延时间隔下爆破振动速度峰值最大值的50%左右。提出的计算公式在实际工程中获得了良好的应用效果,同时验证了该计算公式的可行性。     

基于以太网机群的海量高光谱数据处理系统平台设计

在一些大型图像处理系统中,通过构建服务器机群网络,可实现多台服务器并行处理图像数据流。针对高光谱遥感数据及处理算法特点,设计了基于以太网的服务器机群海量高光谱数据处理系统平台,平台由7台服务器和1台千兆网交换机构组成,其中选择CPU核数不低于8核的4台HP刀片服务器作为并行处理服务器,在服务器机群软件设计中,通过任务分解、算法流水化处理及网络负载均衡等方法来实现并行处理。该系统已应用在某遥感数据处理系统中,多台服务器同时写入SAN盘阵,可实现6 000 Mbps的写入能力。     

Nonlinear progressive damage model for composite laminates used for low-velocity impact

In order to effectively describe the progressively intralaminar and interlam- inar damage for composite laminates, a three dimensional progressive damage model for composite laminates to be used for low-velocity impact is presented. Being applied to three-dimensional （3D） solid elements and cohesive elements, the nonlinear damage model can be used to analyze the dynamic performance of composite structure and its failure be- havior. For the intralaminar damage, as a function of the energy release rate, the damage model in an exponential function can describe progressive development of the damage. For the interlaminar damage, the damage evolution is described by the framework of the continuum mechanics through cohesive elements. Coding the user subroutine VUMAT of the finite element software ABAQUS/Explicit, the model is applied to an example, i.e., carbon fiber reinforced epoxy composite laminates under low-velocity impact. It is shown that the prediction of damage and deformation agrees well with the experimental results.     

Comparative study on the power scaling performance of three different coherent polarization beam combination system structures

Coherent polarization beam combination (CPBC) is a new kind of coherent beam combination configuration with high combining efficiency and excellent beam quality. In order to extend the CPBC system to a large scale, we provide a comparative study on the power scaling performance of three different coherent polarization beam combination system structures. It is found that the pairwise structure has high tolerance to aberrations and has the potential to extend to a large scale with high combining efficiency. In consideration of all the aberrations, the combining efficiency of the pairwise structure can be attained as high as 90% when the combined beams are more than 200. Some instructive suggestions are given to extend the CPBC system to a large scale.     

Thermodynamics Properties of Oxymatrine in NaCl Solution

The enthalpies of dissolution of oxymatrine in 0.9%NaCl solution were measured using a RD496-2000 Calvet Microcalorimeter at 309.65 K under atmospheric pressure. The differen-tial enthalpy and molar enthalpy of oxymatrine dissolution in the 0.9%NaCl solution of were determined. The corresponding kinetic equation that described the dissolution process was elucidated. Moreover, the half-life, molar entropy, molar enthaply, and Gibbs free energy of the dissolution process were also obtained.     

The 260-W coherent beam combining of two compact fibre amplifier chains

Coherent beam combining of two fibre amplifier chains with a total power of 260 W in a compact system using the stochastic parallel gradient descent (SPGD) algorithm is demonstrated. A 150 MHz linewidth fibre laser is built and introduced for high-power amplification to mitigate stimulated Brillouin scattering (SBS). Compact high-power amplifier chains are built with low power all-fibre system and high-power bulk free-optics fibre amplifiers. When the total power is about 260 W, active phase-locking of two high-power amplifiers is demonstrated using the SPGD algorithm. In closed-loop, the power in the main lobe increases 1.68 times, the visibility is increased from 0 to 0.62, and the phase residual error is less than λ/10.     

位点可控的二乙氧磷酰化壳寡糖的合成

以壳寡糖(COS)为原料, 二乙基亚磷酸酯(DEPH)为磷酰化试剂, 通过改变反应体系中三乙胺(TEA)的用量控制二乙基磷酰基的进攻位点, 实现了2-N和3,6-O位点二乙基亚磷酰化壳寡糖衍生物的合成, 制备了N-二乙氧磷酰化壳寡糖及N,O,O-二乙氧磷酰化壳寡糖, 并采用单一变量法对合成条件进行了优化, 用³¹P NMR对产物进行了跟踪分析. 合成N-二乙氧磷酰化壳寡糖的最优反应条件为2 g COS, n_COS∶n_TEA=1∶6, n_COS∶n_DEPH=1∶3, 滴加DEPH和CCl₄的时间为2 h, 低温反应2 h, 在该优化条件下产物的磷含量为1.50%(质量分数). 合成N,O,O-二乙氧磷酰化壳寡糖的最优反应条件为2 g COS, n_COS∶n_TEA=1∶6, n_COS∶n_DEPH=1∶5, 滴加DEPH和CCl₄ 的时间2 h, 低温反应4 h, 常温反应8 h, 在该优化条件下产物的磷含量为3.42%. 对合成反应的可能机理进行了推测.